300+ TOP MCQs on Reversible And Irreversible Reaction and Answers

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MCQs on Reversible And Irreversible Reaction :

1. The net energy change in a reversible cyclic process is
(A) 3/2 RT
(B) zero
(C) always > 0
(D) always < 0

Answer

Answer: (b)

2. Which of the following is an extensive property?
(A) temperature
(B) pressure
(C) mass/volume ratio
(D) energy

Answer

Answer: (d)

3. Which of the following represents the largest amount of energy?
(A) 1 electron volt
(B) 1 erg
(C) 1 calorie
(D) 1 joule

Answer

Answer: (c)

4. Which of the following is correct for an adiabatic process?
(A) 𐤃E = q
(B) q = 0
(C) q = +w
(D) P𐤃 V = 0

Answer

Answer: (b)

5. The mixing of gases is generally accompanied by
(A) decrease in entropy
(B) a decrease in free energy
(C) change in heat content
(D) increase in free energy

Answer

Answer: (b)

6. One litre atmosphere is approximately equal o
(A) 101J
(B) 8.314J
(C) 931J
(D) 19.2J

Answer

Answer: (a)

7. The enthalpy change for a given reaction at 298K is -x J/mol. If the reaction occurs spontaneously at 298K the entropy change at that temperature
(A) can be negative but larger than x/298
(B) can be negative but smaller than x/298
(C) cannot be negative
(D) cannot be positive

Answer

Answer: (b)

8. The initial energy change (𐤃U) of a process does not depend upon
(A) amount of substance undergoing the change
(B) temperature
(C) path of the process
(D) nature of substance undergoing the change

Answer

Answer: (c)

9. Vibrational energy is
(A) partial potential and partly kinetic
(B) only potential
(C) only kinetic
(D) neither kinetic nor potential

Answer

Answer: (a)

10. The total entropy change for a system and its surroundings increases if a process is
(A) exothermic
(B) endothermic
(C) reversible
(D) irreversible

Answer

Answer: (d)

300+ TOP MCQs on Auto Oxidation and Disproportionation and Answers

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MCQs on Auto Oxidation and Disproportionation :

1. Which one of the following will not reduce an acidified solution of potassium dichromate (VI)?
(A) (CH3)2C(OH)CH3
(B) FeSO4
(C) CH3CH2CH(OH)CH3
(D) Zn

Answer

Answer: (a)

2. 25.4g of iodine and 14.2g of chlorine is made to react completely to yield a mixture of ICl and ICl3. Calculate the ratio of moles of ICl and ICl3
(A) 1:1
(B) 1:2
(C) 1:3
(D) 2:3

Answer

Answer: (a)

3. Which of the following has been arranged in order of decreasing average oxidation number of sulphur?
(A) H2S2O7 > Na2S4O6 > Na2S2O3 > S8
(B) SO2+ > SO42- > SO32- > HSO4
(C) H2SO5 > H2SO3 > SCl2 > H2S
(D) H2SO4 > SO2 > H2S > H2S2O8

Answer

Answer: (c)

4. The decomposition of KClO3 to KCl and O2 on heating is an example of
(A) intermolecular redox change
(B) intramolecular redox change
(C) disproportionation or auto redox change
(D) none of these

Answer

Answer: (b)

5. Disproportionation means
(A) only oxidation
(B) only reduction
(C) both, oxidation and reduction of a reactant
(D) neither oxidation nor reduction

Answer

Answer: (c)

6. The compounds behaving both oxidizing, as well as a reducing agent, is
(A) H2O2
(B) SO2
(C) HNO2
(D) HNO3

Answer

Answer: (a,b,c)

7. A substance which can be oxidised as well as reduced easily is
(A) HCl
(B) HClO
(C) HClO3
(D) HClO4

Answer

Answer: (b,c)

8. Equivalent mass of oxidising agent in the reaction

SO2 + 2H2S → 3S + 2H2O
(A) 32
(B) 64
(C) 16
(D) 8

Answer

Answer: (c)

9. The oxidation number of iron in Fe3O4 is
(A) +2
(B) +3
(C) 8/3
(D) ⅔

Answer

Answer: (a,b)

10. Oxidation numbers of chlorine in Cl2O, Cl2 and ClO3 are respectively
(A) +1, -1, +5
(B) +1, 0, -1
(C) -1, 0, +1
(D) +1, 0, +5

Answer

Answer: (d)

300+ TOP MCQs on Aldehydes, Ketones and Carboxylic Acids and Answers

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MCQs on Aldehydes, Ketones and Carboxylic Acids :

1. A mixture of benzaldehyde and formaldehyde on heating with aqueous NaOH solution gives
(A) benzyl alcohol + sodium formate
(B) sodium benzoate + methanol
(C) benzyl alcohol + methanol
(D) sodium benzoate + sodium formate

Answer

Answer: (a)

2. Which of the following has the most acidic hydrogen?
(A) hexane-2,4-dione
(B) hexane-2,3-dione
(C) hexane-2,5-dione
(D) hexane-3-one

Answer

Answer: (a)

3. A new C-C bond formation is possible in
(A) cannizzaro reaction
(B) friedel crafts reaction
(C) clemmensen reduction
(D) reimer tiemann reaction

Answer

Answer: (b,d)

4. Under Wolff-Kishner reduction conditions, the conversions which may be brought about are
(A) cyclohexanone into cyclohexane
(B) benzaldehyde into benzyl alcohol
(C) cyclohexanone into cyclohexanol
(D) benzophenone into diphenylmethane

Answer

Answer: (a,d)

5. The formation of cyanohydrin from a ketone is an example of
(A) electrophilic addition
(B) nucleophilic addition
(C) nucleophilic substitution
(D) electrophilic substitution

Answer

Answer: (b)

6. Benzoic acid reacts with conc.HNO3 and conc.H2SO4 to give
(A) o-nitrobenzoic acid
(B) p-nitrobenzoic acid
(C) m-nitrobenzoic acid
(D) o,p-dinitrobenzoic acid

Answer

Answer: (c)

7. An inorganic compound producing an organic compound on heating is
(A) ammonium cyanate
(B) soda lime
(C) sodamide
(D) potassium cyanide

Answer

Answer: (a)

8. The reaction of ethyl formate with an excess of CH3MgI followed by hydrolysis gives
(A) ethanol
(B) n-propyl alcohol
(C) propanal
(D) isopropyl alcohol

Answer

Answer: (d)

9. Formic acid and acetic acid are distinguished by reaction with
(A) sodium ethoxide
(B) sodium
(C) HgCl2
(D) 2,4-dinitrophenylhydrazine

Answer

Answer: (c)

10. Heating a mixture of sodium benzoate and soda lime gives
(A) calcium benzoate
(B) benzene
(C) sodium benzoate
(D) methane

Answer

Answer: (b)

300+ TOP MCQs on Hydrocarbons and Answers

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MCQs on Hydrocarbons :

1. Find the correct order of increasing acidity
MCQs on Hydrocarbons for NEET 1

Answer

Answer: (d)

2. Identify Z in the given reaction:
MCQs on Hydrocarbons for NEET 2

Answer

Answer: (d)

3. The product obtained on heating 2-Bromopentane with potassium ethoxide in ethanol is
(A) 1-pentene
(B) 2-cis-pentene
(C) trans-2-pentene
(D) 2-ethoxy pentane

Answer

Answer: (c)

4. Choose the process by which liquid hydrocarbons can be converted to gaseous hydrocarbons
(A) hydrolysis
(B) oxidation
(C) cracking
(D) distillation under reduced pressure

Answer

Answer: (c)

5. Which one of the following halide can be used in the Friedel-Crafts reaction?
(A) Isopropyl chloride
(B) Bromobenzene
(C) Chlorobenzene
(D) Chloroethene

Answer

Answer: (a)

6. Which one of the following compound forms salt on reaction with NaNH2?
(A) C2H2
(B) C2H6
(C) C6H6
(D) C2H4

Answer

Answer: (a)

7. Which among the following reagent can be used to distinguish between CH2BrCH=CH2 from CH3CH=CHBr?
(A) Br2/CCl4
(B) cold KMnO4
(C) AgNO3/C2H5OH
(D) Ag(NH3)2OH

Answer

Answer: (c)

8. Isopropyl iodide is formed after reaction of propene with HI, this is due to
(A) more stable free radical
(B) homolysis
(C) more stable carbanion
(D) more stable carbocation

Answer

Answer: (d)

9. C6H5CHO is formed when C6H6 is treated with CO and HCl in the presence of anhydrous AlCl3. Name of the reaction is:
(A) Friedel crafts reaction
(B) Gattermann Koch reaction
(C) Rosenmund reaction
(D) Stephen reaction

Answer

Answer: (b)

10. A compound having a bond angle 180° is
(A) alkyne
(B) alkane
(C) alkene
(D) cycloalkane

Answer

Answer: (a)

300+ TOP MCQs on Alkyne and Answers

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MCQs on Alkyne :

1. Ethyne and Ethane can be separated from a mixture by passing it through
(A) Pyrogallol
(B) Charcoal powder
(C) Concentrated H2SO4
(D) Ammonical Cu2Cl2

Answer

Answer: (d)

2. 1-butyne and 2-butyne can be identified by using which of the following reagents?
(A) O2
(B) Br2
(C) NaNH2
(D) HCl

Answer

Answer: (c)

3. Which of the following is used for welding?
(A) CH4
(B) C2H2
(C) C2H6
(D) C2H4

Answer

Answer: (b)

4. The product formed in the reaction of propyne with dilute H2SO4 and HgSO4 is
(A) Propyl hydrogen sulphate
(B) Propanone
(C) Propanal
(D) Propanol

Answer

Answer: (b)

5. Polymerisation product of propyne is
(A) Benzene
(B) Ethyl benzene
(C) Propyl benzene
(D) Mesitylene

Answer

Answer: (d)

6. The product formed in the reaction of ethyne with dilute H2SO4 and Hg2+ is
(A) Ethyl hydrogen sulphate
(B) Methoxymethane
(C) Ethanal
(D) Ethanol

Answer

Answer: (c)

7. In the ozonolysis reaction, acetylene forms
(A) Formaldehyde
(B) Glycol
(C) Glyoxal, formic acid
(D) None of the above

Answer

Answer: (c)

8. Acetylene is oxidised by KMnO4 to form
(A) Acetic acid
(B) Ethyl alcohol
(C) Ethylene glycol
(D) Oxalic acid

Answer

Answer: (d)

9. Find Z in the following reaction
(A) Ethyl bromide
(B) Ethylene bromide
(C) Ethylidene bromide
(D) Ethanol

Answer

Answer: (a)

10. When ethyne is passed through a red hot tube, _______ is formed
(A) Cyclohexane
(B) Neoprene
(C) Benzene
(D) Ethane

Answer

Answer: (c)

300+ TOP MCQs on Hydrogen Peroxide and Answers

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MCQs on Hydrogen Peroxide :

1. The structure of hydrogen peroxide is
(A) Planar
(B) Spherical
(C) Linear
(D) Non-planar

Answer

Answer: (d)

2. Fenton’s reagent is 
(A) Zn + HCl
(B) Sn + HCl
(C) FeSO4 + H2O2
(D) None

Answer

Answer: (c)

3. Hydrogen peroxide is
(A) oxidising agent
(B) reducing agent
(C) oxidising as well as reducing
(D) None

Answer

Answer: (c)

4. In the disproportionation Hydrogen peroxide, forming H2O and Oits equivalent weight is 
(A) 8.5
(B) 17
(C) 34
(D) 68

Answer

Answer: (c)

5. The gram equivalent weight of H2Oas a reductant is 
(A) 34
(B) 68
(C) 18
(D) 17

Answer

Answer: (d)

6. H2Ocannot oxidise
(A) Na2SO3
(B) O3
(C) PbS
(D) KI/HCl

Answer

Answer: (b)

7. Which of the following contains peroxide linkage?
(A) SO2
(B) MnO2
(C) NO2
(D) BaO2

Answer

Answer: (d)

8. Which of the following statement is false
(A) H2Ois oxidising
(B) H2Ois reducing
(C) H2Ois basic
(D) H2Ois acidic

Answer

Answer: (c)

9. Which of the following gives hydrogen peroxide on electrolysis?
(A) H2SO4
(B) H2O
(C) HCl
(D) None of the above

Answer

Answer: (a)

10. Acidified potassium permanganate is dropped over sodium peroxide taken in a round bottom flask at room temperature, the vigorous reaction takes place to produce
(A) hydrogen peroxide
(B) a mixture of hydrogen and oxygen
(C) a colourless gas hydrogen
(D) a colourless gas dioxygen

Answer

Answer: (d)