250+ TOP MCQs on P-T and T-S diagram for Pure Substance and Answers

Thermodynamics Multiple Choice Questions on “P-T and T-S diagram for Pure Substance”.

1. Which of the following curves meet at triple point?
a) fusion curve and vaporization curve
b) fusion curve and sublimation curve
c) vaporization curve and sublimation curve
d) fusion curve and vaporization curve and sublimation curve
Answer: d
Clarification: At triple point, all these three curves meet.

2. The slopes of sublimation and vaporization curves for all substances are
a) negative
b) positive
c) zero
d) none of the mentioned
Answer: b
Clarification: This is true for all substances.

3. The slope of the fusion curve for water is
a) negative
b) positive
c) zero
d) none of the mentioned
Answer: a
Clarification: The slope of fusion curve for most substances is positive but for water it is negative.

4. The temperature at which a liquid boils is very sensitive to pressure but the temperature at which a solid melts is not such a strong function of pressure.
a) true
b) false
Answer: a
Clarification: The slope of the fusion curve is small.

5. Which of the following statement is true?
a) the triple point of water is 273.16 K
b) the triple point of CO2 is 216.55 K
c) when solid CO2 is exposed to 1atm pressure, it gets transformed into vapour directly
d) all of the mentioned
Answer: d
Clarification: The solid CO2 absorbs the latent heat of sublimation from the surroundings which gets cooled.

6. The equation which forms the basis of the Mollier diagram is
a) Tds=-dh+vdp
b) Tds=dh+vdp
c) Tds=dh-vdp
d) none of the mentioned
Answer: c
Clarification: This equation form the basis of the h-s diagram of a pure substance also called the Mollier diagram.

7. Which of the following statements is true?
a) the slope of an isobar on h-s coordinates is equal to the absolute saturation temperature at that pressure
b) is the temperature remains constant, the slope will also remain constant
c) if the temperature increases, the slope of the isobar will also increase
d) all of the mentioned
Answer: d
Clarification: Here absolute saturation temperature is given by Tsat+273.

8. Which of the following represents the latent heat of vaporization at a particular pressure.
a) Hf-Hg
b) Hg-Hf
c) Hf+Hg
d) none of the mentioned
Answer: b
Clarification: Here Hg is the specific enthalpy of the saturated vapour and Hf is the specific enthalpy of the saturated water.

9. At critical pressure, value of Hg-Hf is
a) two
b) one
c) zero
d) infinity
Answer: c
Clarification: As pressure increases, there is a decrease in Hg-Hf and at critical pressure its value becomes zero.

10.In the Mollier diagram, the constant pressure lines diverge from one another.
a) true
b) false
Answer: a
Clarification: As the pressure increases, the saturation temperature also increases, increasing the slope of the isobar.

250+ TOP MCQs on Energy Equation and Answers

Advanced Thermodynamics Questions & Answers on “Energy Equation”.

1. Superheated R-134a at 0.5 MPa, 20°C is cooled in a piston-cylinder at constant temperature to a final two-phase state with quality of 50%. The refrigerant mass is 5 kg, and during the process 500 kJ of heat is removed. Find the necessary work.
a) -67.9 kJ
b) -77.9 kJ
c) -87.9 kJ
d) -97.9 kJ

Answer: c
Clarification: Energy Eq.: m(u2 -u1) = 1Q2 – 1W2 = -500 – 1W2
State 1: T1,P1, v1 = 0.04226 m3/kg ; u1 = 390.52 kJ/kg
=> V1 = mv1 = 0.211 m3
State 2: T2 , x2 ⇒ u2 = 227.03 + 0.5 × 162.16 = 308.11 kJ/kg,
v2 = 0.000817 + 0.5 × 0.03524 = 0.018437 m3/kg
=> V2 = m(v2) = 0.0922 m3
work = -500 – m(u2 – u1) = -500 – 5 × (308.11 – 390.52) = -87.9 kJ.

2. Air at 600 K flows with 3 kg/s into a heat exchanger and out at 100°C. How much (kg/s) water coming in at 100 kPa, 20°C can the air heat to the boiling point?
a) 0.37 kg/s
b) 0.17 kg/s
c) 0.27 kg/s
d) 0.57 kg/s

Answer: c
Clarification: C.V. :Heat Exchanger, No external heat transfer and no work.
Writing the Steady State Energy Equation (SSEE) and putting values,
we get the water flow rate at the exit is 0.27 kg/s.

3. Nitrogen gas flows into a convergent nozzle at 200 kPa, 400 K and very low velocity. It flows out of the nozzle at 100 kPa, 330 K. If the nozzle is insulated find the exit velocity.
a) 681.94 m/s
b) 581.94 m/s
c) 481.94 m/s
d) none of the mentioned

Answer: d
Clarification: C.V.: Nozzle; steady state; one inlet and exit flow; insulated so it is adiabatic.
SSEE: h1 + 0 = h2 + [(V2)2] / 2
[(V2)2] = 2(h1 – h2) = 2Cp(T1 – T2)
= 2 × 1.042 (400 – 330)
= 145.88 kJ/kg = 145 880 J/kg
V2 = 381.94 m/s.

4. A steam turbine has an inlet of 2 kg/s water at 1000 kPa, 350°C and velocity of 15 m/s. The exit is at 100 kPa, x = 1 and very low velocity. Find the specific work.
a) 382.3 kJ/kg
b) 482.3 kJ/kg
c) 582.3 kJ/kg
d) 682.3 kJ/kg

Answer: b
Clarification: SSEE is W/m = (h1 – h2) + [(V1)2 – (V2)2]/2 + g(z1 – z2)
here z1=z2 and V2=0 hence w = (h1 – h2) + [(V1)2]/2
h1 = 3157.65 kJ/kg, h2 = 2675.46 kJ/kg
wT = 3157.65 – 2675.46 + ½ (152/1000) = 482.3 kJ/kg.

5. A steam turbine has an inlet of 2 kg/s water at 1000 kPa, 350°C and velocity of 15 m/s. The exit is at 100 kPa, x = 1 and very low velocity. Find the power produced.
a) 664.6 kW
b) 764.6 kW
c) 864.6 kW
d) 964.6 kW

Answer: d
Clarification: SSEE is W/m = (h1 – h2) + [(V1)2 – (V2)2]/2 + g(z1 – z2)
here z1=z2 and V2=0 hence w = (h1 – h2) + [(V1)2]/2
h1 = 3157.65 kJ/kg, h2 = 2675.46 kJ/kg
wT = 3157.65 – 2675.46 + ½ (152/1000) = 482.3 kJ/kg
thus power produced = (2 kg/s)(482.3 kJ/kg) = 964.6 kW.

6. 10kg of water in a piston-cylinder exists as saturated liquid/vapour at 100 kPa, with a quality of 50%. It is now heated till the volume triples. The mass of piston is such that a cylinder pressure of 200 kPa will float it. Find the heat transfer in the process.
a) 23961 kJ
b) 24961 kJ
c) 25961 kJ
d) 26961 kJ

Answer: c
Clarification: m(u2 − u1) = 1Q2 − 1W2
Process: v = constant until P = Plift , then P is constant.
State 1: Two-phase; u1 = 417.33 + 0.5 × 2088.72 = 1461.7 kJ/kg
and v1 = 0.001043 + 0.5 × 1.69296 = 0.8475 m3/kg
State 2: v2, P2 ≤ Plift => v2 = 3 × 0.8475 = 2.5425 m3/kg ;
Interpolate: T2 = 829°C, u2 = 3718.76 kJ/kg
=> V2 = mv2 = 25.425 m3
1W2 = P(lift)(V2 −V1) = 200 × 10 (2.5425 − 0.8475) = 3390 kJ
1Q2 = m(u2 − u1) + 1W2 = 10×(3718.76 − 1461.7) + 3390 = 25961 kJ.

7. A 1L capsule of water at 150°C, 700 kPa is placed in a larger insulated (otherwise evacuated) vessel. The capsule breaks resulting which its contents fill the entire volume. If the final pressure is not to exceed 125 kPa, find the vessel volume?
a) 115 L
b) 125 L
c) 135 L
d) 145 L
View Answer

Answer: a
Clarification: m2 = m1 = m = V/v1 = 0.916 kg
Process: expansion with 1Q2 = 0, 1W2 = 0
Energy: m(u2 – u1) = 1Q2 – 1W2 = 0 ⇒ u2 = u1
State 1: v1 = vf = 0.001091 m3/kg; u1 = uf = 631.66 kJ/kg
State 2: P2 , u2 ⇒ x2 =(631.66 – 444.16)/2069.3 = 0.09061
v2 = 0.001048 + 0.09061 × 1.37385 = 0.1255 m3/kg
V2 = m(v2) = 0.916 × 0.1255 = 0.115 m3 = 115 L.

8. A vertical cylinder fitted with a piston contains 5 kg of R-22 at 10°C. Heat is transferred causing the piston to rise until the volume has doubled. Additional heat is transferred until the temperature inside reaches 50°C, at which point the pressure inside the cylinder is 1.3 MPa. Find the work done.
a) 34.1 kJ
b) 44.1 kJ
c) 54.1 kJ
d) 64.1 kJ

Answer: a
Clarification: Process: 1 -> 2 -> 3
As piston floats, pressure is constant (1 -> 2) and the volume is constant for the second part (2 -> 3). So we have: v3 = v2 = 2 × v1
State 3: (P,T) v3 = 0.02015 m3/kg, u3 = 248.4 kJ/kg
v1 = 0.010075 = 0.0008 + x1 × 0.03391 => x1 = 0.2735
u1 = 55.92 + 0.2735 × 173.87 = 103.5 kJ/kg
State 2: v2 = 0.02015 m3/kg, P2 = P1 = 681 kPa this is still 2-phase
Work = P1(V2 – V1) = 681 × 5 (0.02 – 0.01) = 34.1 kJ.

9. A 250L rigid tank contains methane at 1500 kPa, 500 K. It is now cooled down to 300K. Find the heat transfer.
a) –402.4 kJ
b) –502.4 kJ
c) –602.4 kJ
d) –702.4 kJ

Answer: b
Clarification: Assume ideal gas, P2 = P1 × (Τ2 / Τ1) = 1500 × 300 / 500 = 900 kPa
m = P1V/RT1 =(1500 × 0.25)/(0.5183 × 500) = 1.447 kg
u2 – u1 = Cv (T2 – T1) = 1.736 (300 – 500) = –347.2 kJ/kg
1Q2 = m(u2 – u1) = 1.447(-347.2) = –502.4 kJ.

10. A rigid container has 2kg of carbon dioxide gas at 1200 K, 100 kPa that is heated to 1400 K. Find the heat transfer using heat capacity.
a) 231.2 kJ
b) 241.2 kJ
c) 251.2 kJ
d) 261.2 kJ

Answer: d
Clarification: Energy Eq.: U2 – U1 = m (u2- u1) = 1Q2 − 1W2
Process: ∆V = 0 ⇒ 1W2 = 0
For constant heat capacity we have: u2- u1 = Cv (T2- T1)
1Q2 = mCv (T2- T1) = 2 × 0.653 × (1400 –1200) = 261.2 kJ.

11. A piston cylinder contains 3kg of air at 20°C and 300 kPa. It is now heated up in a constant pressure process to 600 K. Find the heat transfer.
a) 941 kJ
b) 951 kJ
c) 961 kJ
d) 971 kJ

Answer: a
Clarification: Ideal gas PV = mRT
P2V2 = mRT2; V2 = mR T2 / P2 = 3×0.287×600 / 300 = 1.722 m3
Process: P = constant, work = ⌠ PdV = P (V2 – V1) = 300 (1.722 – 0.8413) = 264.2 kJ
Energy equation: U2 – U1 = 1Q2 – 1W2 = m(u2 – u1)
Q2 = U2 – U1 + 1W2 = 3(435.097 – 209.45) + 264.2 = 941 kJ.

250+ TOP MCQs on An Overview of Reciprocating Engines and Answers

Thermodynamics Multiple Choice Questions on “An Overview of Reciprocating Engines”.

1. The top dead centre is the position of piston when it forms ____ volume in cylinder and bottom dead centre is the position of piston when it forms ____ volume in cylinder.
a) largest, smallest
b) smallest, largest
c) equal, equal
d) none of the mentioned
Answer: b
Clarification: This is the definition of TDC and BDC.

2. The distance between TDC and BDC is called ____
a) piston
b) bore
c) stroke
d) none of the mentioned
Answer: c
Clarification: It is the largest distance that piston can travel in one direction.

3. The diameter of piston is called ____
a) piston
b) bore
c) stroke
d) none of the mentioned
Answer: b
Clarification: This is what a bore means.

4. The air or air-fuel mixture is ____ into cylinder through intake valve and ____ out of cylinder through exhaust valve.
a) drawn, expelled
b) taken, thrown
c) both of the mentioned
d) none of the mentioned
Answer: c
Clarification: This is what an intake valve and exhaust valve does.

5. The clearance volume is the ____ volume formed in cylinder when piston is at TDC.
a) minimum
b) maximum
c) average
d) none of the mentioned
Answer: a
Clarification: When the piston is at TDC, the volume is minimum.

6. The volume displaced by piston when it moves between TDC and BDC is called
a) swept volume
b) displacement volume
c) clearance volume
d) none of the mentioned
Answer: b
Clarification: Displacement volume is, how much the piston gets displaced when it moves from TDC to BDC and vice-versa.

7. The compression ratio is given by
a) Vmax / total volume
b) Vmin / Vmax
c) V(at TDC) / V(at BDC)
d) V(at BDC) / V(at TDC)
Answer: d
Clarification: The compression ratio of an engine is given by V(at BDC) / V(at TDC) which is also equal to Vmax / Vmin.

8. The net work produced during a cycle is given by
a) (mean effective pressure)*(piston area)*(stroke)
b) (mean effective pressure)*(displacement volume)
c) both of the mentioned
d) none of the mentioned
Answer: c
Clarification: The mean effective pressure is a fictitious pressure.

9. The compression ratio is a pressure ratio.
a) true
b) false
Answer: b
Clarification: The compression ratio is a volume ratio.

10. Which of the following is a classification of reciprocating engines?
a) spark-ignition engines
b) compression-ignition engines
c) both of the mentioned
d) none of the mentioned
Answer: c
Clarification: These two are classified based on how combustion process is initiated in the cylinder.

11. Which of the following statement is true?
a) in S.I. engines, combustion of air-fuel mixture is initiated by spark plug
b) in C.I. engines, combustion of air-fuel mixture is self-ignited
c) both of the mentioned
d) none of the mentioned
Answer: c
Clarification: In the C.I. engines,self-ignition takes place because of compression of mixture above self-ignition temperature.

12. A gasoline engine has a volumetric compression ratio of 10. Find the overall cycle efficiency.
a) 0.602
b) 0.302
c) 0.502
d) 0.702
Answer: a
Clarification: η = 1 − r^(1-k)
= 1 − 10^(-0.4)
= 0.602.

250+ TOP MCQs on Normal Shocks and Answers

Thermodynamics Multiple Choice Questions on “Normal Shocks”.

1. Shock waves are highly localized irreversiblities in flow.
a) true
b) false

Answer: a
Clarification: This is a basic fact about shock waves.

2. Normal shocks can be treated as shock waves parallel to the flow.
a) true
b) false

Answer: b
Clarification: Normal shocks can be treated as shock waves perpendicular to the flow.

3.Within the mean free path of molecule, flow passes from
a) supersonic state
b) subsonic state
c) subsonic to supersonic state
d) supersonic to subsonic state

Answer: d
Clarification: This happens within distance of mean free path of molecule.

4. When flow passes from supersonic to subsonic state,
a) pressure increases
b) velocity decreases
c) both of the mentioned
d) all of the mentioned

Answer: c
Clarification: As velocity decreases, pressure increases.

5. The impulse function is given by
a) F = p*A + (density)*A*(V2)
b) F = p*A + (density)*A*V
c) F = p*A + (density)*A*sqrt(V)
d) none of the mentioned

Answer: a
Clarification: This is the impulse function.

6. Fanno line represents the locus of points with same mass velocity and stagnation enthalpy.
a) true
b) false

Answer: a
Clarification: The Fanno line can be represented on h-v coordinate or h-(1/density) coordinate.

7. The end states of normal shock must ____ Fanno line.
a) lie below
b) lie above
c) lie on
d) none of the mentioned

Answer: c
Clarification: They must lie on the Fanno line.

8. Which of the following is true about adiabatic flow in constant area duct with friction?
a) it has constant G
b) it has constant ho
c) it follows Fanno line
d) all of the mentioned

Answer: d
Clarification: This is true for adiabatic flow in one directional model.

9. The impulse pressure(I) is given by
a) F/A
b) p + (density)(V2)
c) p + (G2)/(density)
d) all of the mentioned

Answer: d
Clarification: These all are the relations of impulse pressure.

10. Rayleigh line represents the locus of states with same impulse pressure and mass velocity.
a) true
b) false

Answer: a
Clarification: The end states of normal shock must lie on Rayleigh line also.

250+ TOP MCQs on Other types of Work Transfer-1 and Answers

Thermodynamics Multiple Choice Questions on “Other types of Work Transfer-1”.

1. The current flow, I, in amperes, is given by I=(dC)/(dτ)
a) dC is the charge crossing a boundary
b) time taken is dτ
c) c is the charge in coulombs and t is time in seconds
d) all of the mentioned
Answer: d
Clarification: This current flow is responsible for the work transfer.

2. Shaft uses which kind of motion to do work?
a) vertical motion
b) horizontal motion
c) rotational motion
d) none of the mentioned
Answer: c
Clarification: When a shaft is rotated by a motor, there is work transfer into the system.

3. Shaft work is given by
a) T*ω
b) T*dθ
c) T*τ
d) none of the mentioned
Answer: a
Clarification: Shaft power is the rate if doing shaft work.

4.The flow work is significant only in
a) flow process
b) open system
c) both of the mentioned
c) none of the mentioned
Answer: c
Clarification: Condition for the flow work.

5. Flow work is analogous to
a) shaft work
b) electrical work
c) stirring work
d) displacement work
Answer: d
Clarification: Flow work is the displacement work done at the moving system boundary.

6. The infinitesimal amount of work done on changing the length of a wire with tension T from L to L+dL is
a) -FdL
b) FdL
c) -2FdL
d) 2FdL
Answer: a
Clarification: It is the work done in stretching a wire.

7. Work done in stretching a wire is given by
a) -∫FdL
b) -∫EɛALdɛ
c) -AEL∫ɛdɛ
d) all of the mentioned
Answer: d
Clarification: Above formulae arrive when we limit the problem within the elastic limit.

8. The surface tension acts to make the surface area of the liquid
a) maximum
b) minimum
c) zero
d) none of the mentioned
Answer: b
Clarification: Characteristic of surface tension.

9. The work done per unit volume on a magnetic material is dW=-Hdl where H is
a) field strength
b) magnetization field
c) induced current
d) none of the mentioned
Answer: a
Clarification: H is the field strength of the magnetic field.

10. The work is equal to the integral of the product of an intensive property.
a) true
b) false
Answer: a
Clarification: Along with it, change in work is related to the extensive property.

11. A 1200 hp engine has a drive shaft rotating at 2000 RPM. Find the torque on the shaft?
a) 2214 Nm
b) 3214 Nm
c) 4214 Nm
d) 5214 Nm
Answer: c
Clarification: Power, rate of work = T ω and 1 hp = 0.7355 kW = 735.5 W
ω = RPM × (2π)/(60 s) = 209.44 rad/s
T = power/ω = (1200 hp × 735.5 W/hp)/ 209.44 rad/s
= 4214 Ws = 4214 Nm.

12. A 1200 hp engine drives a car with a speed of 100 km/h. Find the force between the tires and the road?
a) 11.8 kN
b) 21.8 kN
c) 31.8 kN
d) 41.8 kN
Answer: c
Clarification: Power = F V and 1 hp = 0.7355 kW = 735.5 W
velocity in m/s: V = 100 × 1000 / 3600 = 27.78 m/s
F = (1200 × 735.5)/(27.78) = 31 771 N
= 31.8 kN.

13. A work of 2.5 kJ is delivered on a rod from a piston/cylinder where the air pressure is 500 kPa. What should be the diameter of cylinder to restrict the rod motion to maximum 0.5 m?
a) 0.013 m
b) 0.113 m
c) 0.213 m
d) 0.313 m
Answer: b
Clarification: W = ⌠P dV = ⌠PA dx = PA ∆x = P(π/4)(D^2)∆x
Putting the values in above equation we get
D = 0.113 m.

14. A force of 1.2 kN moves a car with 60 km/h up a hill. Find the power?
a) 20 kW
b) 30 kW
c) 40 kW
d) 50 kW
Answer: a
Clarification: Power = F V = 1.2 kN × 60 (km/h)
= ( 1.2 × 10^3 × 60 )*(1000/3600)
= 20 000 W = 20 kW.

15. When a battery(12 V) is charged with 6 amp for 3 hours how much energy is delivered?
a) 477.6 kJ
b) 577.6 kJ
c) 677.6 kJ
d) 777.6 kJ
Answer: d
Clarification: W = ⌠(power)dt = V i ∆t
= 12 V × 6 Amp × 3 × 3600 s
= 777 600 J = 777.6 kJ.

250+ TOP MCQs on Refrigerator and Heat Pump and Answers

Thermodynamics Multiple Choice Questions on “Refrigerator and Heat Pump”.

1. Which device maintains a body at a temperature lower than the temperature of the surroundings?
a) PMM1
b) PMM2
c) refrigerator
d) heat pump
Answer: c
Clarification: This is the main function of a refrigerator.

2. What does a refrigerant do?
a) absorbs the heat leakage into body from surroundings
b) evaporates in the evaporator
c) absorbs latent heat of vaporization form the body which is cooled
d) all of the mentioned
Answer: d
Clarification: Refrigerant is required for the proper functioning of a refrigerator.

3. Coefficient of performance(COP) is defined as
a) heat leakage/work input
b) work input/heat leakage
c) latent heat of condensation/work input
d) work input/latent heat of condensation
Answer: a
Clarification: Coefficient of performance is the performance parameter used in a refrigerator cycle.

4. Which device maintains a body at a temperature higher than the temperature of the surroundings?
a) PMM1
b) PMM2
c) refrigerator
d) heat pump
Answer: d
Clarification: This is the main function of a heat pump.

5. In a heat pump, there is heat leakage from the body to the surroundings.
a) true
b) false
Answer: a
Clarification: This is just opposite to a refrigerator.

6. What is the relation between COP of heat pump and refrigerator?
a) COP of pump=COP of refrigerator – 1
b) COP of pump=COP of refrigerator + 1
c) COP of pump=COP of refrigerator – 2
d) COP of pump=COP of refrigerator + 2
Answer: b
Clarification: This relation comes from the COP of pump and refrigerator.

7. Heat leakage from a heat pump to surroundings is always greater than work done on pump.
a) true
b) false
Answer: a
Clarification: (Heat leakage from a heat pump to surroundings)=(COP of refrigerator + 1)*(work done on pump).

8. Which of the following statements are true?
a) a heat pump provides a thermodynamic advantage over direct heating
b) COP for both refrigerator and pump cannot be infinity
c) work input for both refrigerator and pump is greater than zero
d) all of the mentioned
Answer: d
Clarification: W is the electrical energy used to drive the pump or refrigerator which cannot be zero.

9. Kelvin-Planck’s and Clausius’ statements are
a) not connected to each other
b) virtually two parallel statements of second law
c) violation of one doesn’t violate the other
d) none of the mentioned
Answer: b
Clarification: Kelvin-Planck’s and Clausius’ statements are equivalent in all aspects.

10. If one of the Kelvin-Planck’s or Clausius’ statement is violated, then other is also violated.
a) true
b) false
Answer: a
Clarification: This shows the equivalence of Kelvin-Planck’s and Clausius’ statements.