Physics Multiple Choice Questions on “Atomic Spectra”.
1. Which source is associated with a line emission spectrum?
a) Electric fire
b) Neon street sign
c) Red traffic light
d) Sun
Answer: b
Clarification: Neon street sign gives a line emission spectrum. When neon atoms gain enough energy to become excited, light is produced. Atom releases a photon when it returns to a lower energy state. Therefore, the source associated with a line emission spectrum is the neon street sign.
2. According to the uncertainty principle for an electron, time measurement will become uncertain if which of the following is measured with high certainty?
a) Energy
b) Momentum
c) Location
d) Velocity
Answer: a
Clarification: According to the uncertainty principle,
ΔE.Δt >= (frac {h}{2pi }).
Thus the time measured will become uncertain if ΔE is measured with high certainty.
3. Find the true statement.
a) An electron will not lose energy when jumping from the 1st orbit to the 3rd orbit
b) An electron will not give energy when jumping from the 1st orbit to the 3rd orbit
c) An electron will release energy when jumping from the 1st orbit to the 3rd orbit
d) An electron will absorb energy when jumping from the 1st orbit to the 3rd orbit
Answer: d
Clarification: An electron will absorb energy when jumping from the 1st orbit to the 3rd orbit. Only by absorbing energy, an electron will be able to jump from the first orbit to the third orbit in the atomic spectrum.
4. The size of the atom is proportional to which of the following?
a) A
b) A1/3
c) A2/3
d) A-1/3
Answer: b
Clarification: The size of the atom is proportional to A1/3.
The electron affinity of the atom is inversely proportional to the atomic size. As the number of energy levels increases, the atomic size must increase.
5. Calculate the ratio of the kinetic energy for the n = 2 electron for the Li atom to that of Be+ ion?
a) (frac {9}{16})
b) (frac {3}{4})
c) 1
d) (frac {1}{2})
Answer: a
Clarification: (frac {KE_{Li}}{KE_{Be}} = big [ frac {(frac {Z_{Li}}{2} )}{(frac {Z_{Be}}{2})} big ]^2 )
(frac {KE_{Li}}{KE_{Be}} = big [ frac {(frac {3}{2} )}{(frac {4}{2})} big ]^2 )
(frac {KE_{Li}}{KE_{Be}} = frac {9}{16}).
6. The Bohr model of atoms uses Einstein’s photoelectric equation.
a) True
b) False
Answer: b
Clarification: Bohr model assumes that the angular momentum of electrons is quantized. Therefore, the Bohr model of the atoms involved is independent of Einstein’s photoelectric equation.
7. What is the ratio of minimum to maximum wavelength in the Balmer series?
a) 5:9
b) 5:36
c) 1:4
d) 3:4
Answer: a
Clarification: For a wavelength of Balmer series,
(frac {1}{lambda }) = R( [ frac {1}{4} – frac {1}{9} ] )
(frac {1}{lambda } = frac {5R}{30}).
(frac {lambda_{min}}{lambda_{max}} = frac {5R}{36} times frac {4}{R} )
(frac {lambda_{min}}{lambda_{max}} = frac {5}{9})
8. The energy of characteristic X-ray is a consequence of which of the following?
a) The energy of the projectile electron
b) The thermal energy of the target
c) Transition in target atoms
d) Temperature
Answer: c
Clarification: The energy of characteristic X-ray is a consequence of transition in target atoms. They cause emission or absorption of electromagnetic radiation. The other options are not responsible for the energy of characteristic X rays.
9. Find out the minimum energy required to take out the only one electron from the ground state of Li+?
a) 13.6 eV
b) 122.4 eV
c) 25.3 eV
d) 67.9 eV
Answer: b
Clarification: Ionization energy is given as:
E = 13.6 Z2 eV
For Li+, Z = 3
E = 13.6 × 9
E = 122.4 eV
10. What is the energy required to ionize an H-atom from the third excited state, if ground state ionization energy of H-atom is 13.6 eV?
a) 1.5 eV
b) 3.4 eV
c) 13.6 eV
d) 12.1 eV
Answer: a
Clarification: From third excited state, E = (frac {-13.6}{16})
E = -0.85 eV
Energy required to ionize H-atom from second excited state = 0 – (-0.85)
E = +0.85 eV