A thermodynamic system in which there is a change in the state of matter due to the change in the Pressure, Volume, Temperature (P, V, T) without transferring heat or mass with the thermodynamic system or its surroundings.
The process in which the work done is in the form of a change in internal energy (U) and the amount of heat transferred, Q is zero (or there is no gain or loss of heat)
On this page, we shall learn about the various topics:
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Adiabatic process
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Related examples
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Derivation of the Adiabatic Process formula
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Work done
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Adiabatic expansion and compression
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Adiabatic- Reversible and Irreversible Process.
There are four types of processes in a thermodynamic system, which are shown via an image below:
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Adiabatic Process: It can be considered as an ideal process in which there is no heat transfer and the change in internal energy would be equal to the work done.
Here, ∆U = U₂ – U₁ ,and W =- ∆U = U1 – U2
W = – ∆U
Since there is no heat transfer that’s why the Entropy (∆S) = 0.
Used in –
Turbines, Hot water flask, compression, and expansion of charge in IC.
Adiabatic Compression and Expansion
Adiabatic Compression
Pressure ( P) > Volume (V)
T, S, and U increase during compression.
In cylinders of a car, the compression of the gas-air mixture takes place in no time that there could be an exchange of heat between them.
Adiabatic Expansion
The work is done by the gas in expanding the volume and there’s a decrease in the temperature.
Let’s take an example here,
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In picture 1, the molecules of a gas are tightly bound together as soon as the membrane is punctured, the volume of the gas expands to Volume dV, and a drop in temperature by dT.
In this case, the work done by a gas W = PdV and dQ = 0.
For an Adiabatic Process for an ideal gas is given by:
PV r = Constant
Work Done in an Adiabatic Expansion
Consider a mole of gas contained in a cylinder having insulating walls, provided with a frictionless and insulating piston
Let P be the pressure of the gas when the piston moves up through a small distance dx, the work done will be:
dW = PAdx = PdV
Where A is the cross-sectional area of the piston and dV = Adx is the increase in the volume.
As the gas expands adiabatically, there will be a change in its initial stage (P1, V1, T1) to (P2, V2, T2).
The total work done will be:
v₂
W = ∫ PdV……(1)
v₁
For an adiabatic change,
PV r = G or P = G* V – r Putting it in eq..1
$w = int_{v1}^{v2}G*V^{-r} dv$
$= G int_{v1}^{v2}V^{-r}dv$
v₂
= G * [ V(1-r)1-r ]
v₁
= G/ (1-r) * [ V₂ (1 – r) – v₁ (1 – r)]
= G/ (r -1) * [v₁ (1 – r) – v₂ ( 1 – r)]
= 1/ (r -1) * [G* v₁ (1 – r) – G * v₂ (1 – r)] …….(2)
G = P₁ V₁ r = P₂ V₂ r…putting in eq (2)
W (adia) = 1/ (r – 1) * [( P₁Vr₁ * V₁ (1-r ) – P₂Vr₂ * V₂ (1-r)]
W(adia) = 1 / (r – 1) *
(P1V1−P2V2)
P1V1−P2V2)……(3)
Deriving an Adiabatic Equation
Adiabatic relationship between P and V
According to the first law of thermodynamics:
dQ = dU + dW….(1)
For one mole of gas, the equation is:
dW = PdV
dU = nCVdT, and CV = dU/dT => dU = nCVdT = CVdT (as n=1)
Also, for an adiabatic process, dQ = 0;
According to the ideal gas equation:
PV= RT…..(2) (n =1)
Now putting the values of dU and dW in equation(1):
0 = CVdT + PdV…..(3)
Differentiating both the sides in equation (2), we get:
PdV + VdP = RdT
dT= (PdV + VdP)/ R
Putting the value of dT in q..(3)
CV (PdV + VdP)/ R + PdV = 0
CV (VdP) + CV + R (PdV)…(4)
As we know that CP = CV + R putting it in eq..(4)
CV (VdP) + CP (PdV) = 0
Dividing both the sides by CVPV, we get:
dP/P + (Cp/Cv)* dV/V = 0
We know that Cp / Cv = r
dP/P + r* dV/V = 0…….(5)
Integrating both the sides in eq…(5)
= ∫ dP/P + r ∫ dV/V = C (∵ C, an integral constant)
= Loge P + r Logₑ V = C
= Loge PV r = C
= PV r = ec
= PV r = G
Adiabatic Relation Between P and T
We already know that for an ideal gas, the equation is given by,
PV = RT ( for one mol gas)
V = RT/P…(1)
Putting the value of equation (1)….in the equation PVr= K
P(RT/P) r = G
= P (1 – r) Tr = G (Constant)
Adiabatic Relation Between V and T
For one mole of gas, PV= RT
P =RT/V
Putting PV r =G, we get
RT/V * Vr = G or T*V(r – 1) = G/ R
= TV(r – 1) = G (Constant)
This equation describes the adiabatic relation between V and T for an ideal gas.
Adiabatic – Reversible and Irreversible process
Reversible Adiabatic Process
A reversible adiabatic process is basically an isentropic process.
What is an Isentropic Process?
Since in an adiabatic process, the heat transfer is zero which means the change in entropy is also zero. That’s why the process is said to be isentropic by nature.
As, S (entropy) =dQ/ dT
dQ will be zero because there is no heat transfer, dQ/ dT = 0
d(S) = 0
Let’s Consider Some Real-Life Examples:
PVr is constant along a reversible adiabatic process.
Irreversible Adiabatic Process
As the name suggests, the process can’t be traced back to its original state.
During an irreversible adiabatic process of expansion. There will be a change in entropy because of frictional dissipation.
Irreversible expansion cannot be performed at equilibrium.
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Summary
An Irreversible process can’t be in a quasi-static state (the process that happens slowly to keep it in an equilibrium)
A reversible process is a quasi-static process.
Application-Based Questions
1. Let’s take an example of the daily based activity, of pumping air inside the tire of a bicycle using a hand pump. Here, we would consider air inside the pump is a thermodynamic system having Volume V at an atmospheric pressure P, and the room temperature, 30°C. Suppose the nozzle of the tire is blocked and you push the pump to ⅕ of the volume V. Calculate the final temperature of the air in the pump.
Solution: Since the nozzle of the tire is blocked air will not flow, we will consider this as an Adiabatic Process
Ti Vi (r -1) = Tf Vf (r – 1)
Ti = 30°C = (273 + 30) K = 303 K
Vi = V , so Vf = V/5
Tf = Ti *(Vi / Vf)(r -1)
= 303 K* 5(1.4 -1)
= 303 K * 50.4
= 303 * 1.90365
Tf = 576.81 K
Since the temperature T is very high it is dangerous to touch the nozzle.
Q2: Two cylinders A and B of equal size (both fitted with piston) are filled with an equal amount of ideal gas at room temperature. In-cylinder A the piston is free to
move, while in B, it is fixed. When some amount of heat is added to cylinder A raises by 30 K. What will be the rising temperature of the gas in cylinder B?
Solution: For gas in cylinder A,
Q (heat) = n x CpdT1, and that for cylinder B = n x CvdT2
So, dT2 = Cp/ Cv x dT1
= 7/5 x 30.
(Here, Cp/ Cv = 7/5)
dT2 = 42 K (dT2 = Rise in temperature in cylinder B).