[Chemistry Class Notes] on Sodium Iodide Pdf for Exam

Sodium iodide is a salt that is formed by the ionic reaction of sodium metal and iodine. The sodium iodide formula is NaI. Under standard conditions, it is a white, soluble solid which includes a 1:1 blend of sodium cations (Na+) and iodide anions (I−) in a lattice grid. Its main uses are in the field of medicine as a nutritional supplement and as additives. It is created when the salt is produced when acidic iodides respond with sodium hydroxide. It is a chaotropic salt. Sodium iodide is a metal iodide salt with a Na(+) counterion. It is an inorganic sodium salt and an iodide salt. 

Sodium iodide has many interesting chemical and physical properties. It is created by the combination of an acid and a base yielding no by‐products.

The physical properties of sodium iodide are mentioned below.

  • The melting point of sodium iodide is 661 degrees C. 

  • The boiling point of sodium iodide is 1304 degrees Celsius.

  • It is a strong deliquescent, which absorbs moisture and transforms into a solution. 

  • It is a white and odourless crystal or powder

Properties of Sodium Lodide

Property Value Name 

Property

Molecular Weight 

149.8942 g/mol

Hydrogen Bound Donar Count

0

Hydrogen Bond Acceptor Count

1

Rotatable Bond Count

0

Exact Mass

149.89424 g/mol

Monoisotopic Mass

149.89424 g/mol

Topological Polar Surface Area

0 A2

Heavy Atom Count 

2

Chemical Properties Of Sodium Iodide

Sodium iodide is extremely soluble in water and has an ionic crystal lattice structure.

Sodium iodide structure is given below:-

Sodium iodide is not only dissolvable in water but also some other natural solvents. It is affected by air, moisture, and light, and strong NaI solid turns brownish colored on introduction to air or light, because of the development of iodine gas. It additionally responds explosively with various oxidants, solid acids, and bromine trihalides, creating iodine.

Iodides (counting sodium iodide) are oxidized by oxygen strongly (O2) to iodine gas(I2).

The resultant I2 and I-complex which is formed as a byproduct end up shaping the triiodide complex, which is rather yellow in color, in contrast to the white shade of sodium iodide. 

Water quickens the oxidation procedure, and iodide can likewise create I2 gas by simple photooxidation. This is one of the biggest reasons sodium iodide ought to be put away under dim lights, low temperature, and low moisture conditions. It is better to maintain precautions and keep the solid away from external elements. 

NaI + Cl2 —–> NaCl + I2

NaI + 4H2O ——> [Na(H2O)4]+  + I

Hot sodium will likewise react along with halogen elements such as bromine or iodine gas fumes to create sodium bromide or sodium iodide. Every one of the usual reactions which result in the formation of sodium iodide gives out an orange fire and a white solid ionic lattice structure. 

Iodide has a negative charge which implies it holds additional electrons which act as its valency. When it can obtain other iodine atoms it can lose the electrons to form stable I2 gas. The lost electrons will be picked up by another dependent atom or molecule which will be reduced into making iodide a good reducing agent. 

Uses of Sodium Lodide

  • Sodium iodide is regularly utilized as a dietary iodine supplement and used to prepare pure NaCl as for table salt (NaCl).  It is used to treat and prevent iodine deficiency. This disease can adversely affect the endocrine system. But NaI can help alleviate the symptoms by providing a source of iodine. 

  • Another regular usage of (Sodium iodide formula) NaI is in atomic medication, as radioactive sodium iodide, (for example, NaI125 and NaI131) . Its similar subordinates are significant radiopharmaceuticals that are utilized for stopping and preventing thyroid malignant growth and hyperthyroidism, and furthermore as imaging tracers. 

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