Chemistry MCQs for Schools on “Solid State – Packing Efficiency”.
1. What does the ratio ‘space occupied/total space’ denote?
a) Packing factor
b) Packing efficiency
c) Particle fraction
d) Packing unit
Answer: a
Clarification: Packing factor is a fraction of total space of the unit cell occupied by the constituent particles.
2. What is the dimensional formula of packing fraction?
a) M0L3T0
b) M0L0T0
c) ML0T0
d) M0L2T0
Answer: b
Clarification: Packing fraction is a dimensionless quantity which is the ratio of space occupied to total crystal space available. Since both the quantities have the same units the ratio renders dimensionless.
3. Arrange the types of arrangement in terms of decreasing packing efficiency.
a) BCC b) HCP c) HCP d) CCP Answer: c
Clarification: HCP and CCP have the highest packing efficiency of 74% followed by BCC which is 68%. The simple cubic structure has a packing efficiency of 54%.
4. If the body-centered unit cell is assumed to be a cube of edge length ‘a’ with spherical particles of radius ‘r’ then how is the diameter, d of particle and surface area, S of the cell related?
a) S = 32d4/3
b) S = 2d2
c) S = 4d2
d) S = 8d2
Answer: d
Clarification: For BCC unit cell the relation between radius of a particle ‘r’ and edge length of unit cell, a, is r = (frac{sqrt{3}}{4})a.
We know that diameter, d = 2r = (frac{sqrt{3}}{2})a
Implying d2 = (frac{3}{4})a2
Therefore, 4d2/3=a2
Multiplying by 6 on both sides gives S = 6a2 = 8d2, where S is the surface area of the cube = 6a2.
5. Which of the following metals would have the highest packing efficiency?
a) Copper
b) Potassium
c) Chromium
d) Polonium
Answer: a
Clarification: Copper metal bears face-centered unit cells in its crystal structure. Potassium and chromium both have body-centered unit cells whereas polonium is the only known metal to bear a simple cubic structure. FCC structure has the highest efficiency.
6. “The packing efficiency can never be 100%”. Is this true or false?
a) False
b) True
Answer: b
Clarification: Packing efficiency can never be 100% because in packing calculations all constituent particles filling up the cubical unit cell are assumed to be spheres.
7. What are the percentages of free space in a CCP and simple cubic lattice?
a) 52% and 74%
b) 48% and 26%
c) 26% and 48%
d) 74% and 52%
Answer: c
Clarification: The packing efficiency in CCP and simple cubic lattice are 74% and 52%, respectively. Hence the corresponding free spaces will be 100% – 74% = 26% and 100% – 52% = 48%.
8. How many atoms surround the central atom present in a unit cell with the least free space available?
a) 4
b) 6
c) 8
d) 12
Answer: d
Clarification: FCC, CCP and HCP are unit cells with least free space available i.e. highest packing efficiency. The coordination number of given cells are 12.
9. If metallic atoms of mass 197 and radius 166 pm are arranged in ABCABC fashion then what is the surface area of each unit cell?
a) 1.32 × 106 pm2
b) 1.32 × 10-18pm2
c) 2.20 × 105 pm2
d) 2.20 × 10-19 pm2